Originally Posted by
petrified.rabbit
i once put a thermostat in a maintenance, and the car overheated the first time i started it. put in another thermostat, problem went away..
not saying that is your issue, your description suggests the fans, but since you say they are working properly i would do the thermostat again I guess. But a bad thermostat would keep the rad cool, meaning your AC would not get hot.
now when you say you did a hydrocarbon block test, what did you test? a sniffer looking for escaped exhaust around the head? or the dye test of the coolant? If the head gasket is compromised, it does not always leak out of the side go the block. But If the coolant heated up and boiled with the cap off, how long did it take? I have let 4 cylinders idle a long time without them boiling over (10-20minutes) so if it boiled over quickly, you might want to do a cylinder leak down test to see if the head gasket is blown to the oil or, more likely in this case, water jacket.