Having a 6th gear would make no difference since gear 1 thru 5 would be significantly shorter ratio then they are now, making the 6th gear pretty much the same as the current 5th gear.
You will gain acceleration thru the gears but the drive ratio in 6th will still make the engive rev over 3k at highway speeds.
The only way to change that is by modifying the ratio of 5th gear so that its way longer then the others, then you could achieve a 2k or whatever you want rpm at highway speeds.